Crystal structure of di-μ2-chlorido-bis[(1-aza-4-azoniabicyclo[2.2.2]octane-κN 1)dichloridodicadmium]
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چکیده
In the structure of the binuclear title compound, [Cd2(C6H13N2)2Cl6], two Cd(II) atoms are bridged by two Cl(-) ligands, defining a centrosymmetric Cd2Cl2 motif. Each metal cation is additionally coordinated by two Cl(-) ligands and the N atom of a protonated 1,4-di-aza-bicyclo-[2.2.2]octane (H-DABCO)(+) ligand, leading to an overall trigonal-bipyramidal coordination environment with one of the bridging Cl(-) ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linked via N-H⋯Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100).
منابع مشابه
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